Chemistry

Electrolysis

By Examguru / 16 Apr, 2024 / Download PDF

Electrolysis

1. Electrolytes:

These are the substances which allow the electricity to pass through them in their molten states or in the form of their aqueous solution and undergo chemical decomposition, Examples – acids, bases & salts.

2. Strong electrolytes:

The electrolytes which are almost completely dissociated into ions in solution are called strong electrolytes, Example – NaCl, KCl, HCl, NaOH etc.

3. Weak electrolytes:

The electrolytes which do not ionize completely in solution are called weak electrolytes, Example – CH3COOH, H2CO3, HCN, ZnCl2 NH4OH etc.

4. Electrolysis:

The process of chemical decomposition of an electrolyte by passage of electric current through its molten state or its solution is called electrolysis.

5. Electrodes:

In order to pass the current through an electrolytes in molten state or in aqueous solution, two roads or plates are needed to connect with the terminal of a battery. These roads or plates are called electrodes.

Anode:

The electrode which is attached to positive terminal of battery is called anode. Oxidation occurs at anode.

Cathode:

The electrode which is attached to negative terminal of batteries is called, Reduction occurs at cathode.

Examples – Electrolysis of molten NaCl

At anode:       Cl   –   e   →   Cl

                        Cl    +   Cl  →  Cl2

At cathode:    Na+  +   e   →   Na

So, Cl2 gas occurs at anode which Na at cathode.

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